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First off, I’m late for work. Classic me. I rush outta my apartment on Via Vittorio Emanuele, and boom! I trip over a stray cat. Like, c’mon, dude! You gotta watch where you’re going! I’m already in a bad mood. I swear that cat looked at me like, “You think you’re better than me?”
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Further investigations on thermal cis→trans reconversion kinetics confirm the stability of the final compound, accordingly to the NMR results. In fact, keeping irradiated solutions of the azopeptide 1 48 h in the dark at 50°C, only half trans form is thermally recovered, while for azobenzene and α-helix short peptide chain derivatives the recovery is complete, on this time scale, also at room temperature (Kumita et al., 2000). We also decided to investigate the use of ACN/water 1:1 mixture to analyze the effect of organic cosolvent on azopeptide folding.Pietraperzia Brothel
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